## Abstract Reaction of the 3,5βdiarylβ1,2βdithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ringβopened intermediate, which undergoes an intramolecular DielsβAlder cyclization. Compounds 6 and 10 rearrange by treatment wit
Ring-Opening Reactions of 3,5-Bis(methylthio)-1,2-dithiolium Salts with Cyclopentadienides
β Scribed by Hartke, Klaus ;Popp, Xue-Ping
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 624 KB
- Volume
- 1996
- Category
- Article
- ISSN
- 0947-3440
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β¦ Synopsis
π SIMILAR VOLUMES
the line-shape changes allow the detection of two different dynamic processes, which may be assigned to inhibited rotations about the partial C C and C N double bonds of the E-isomers (Scheme 2). Above ca. 0Β°C conversion into the isomer with Z-configurated CC double bond, which contains an intramol
Two new series of 1,1 0 -carbonyl-bis[3-aryl(heteroaryl)-5-trihalomethyl-1H-pyrazoles], where aryl ΒΌ C 6 H 5 , 4-CH 3 C 6 H 4 , 4-FC 6 H 4 , 4-OCH 3 C 6 H 4 , 4-NO 2 C 6 H 4 , 4,4 0 -BiPh, 1-naphthyl, and heteroaryl ΒΌ 2thienyl and 2-furyl have been synthesized, in a one-pot methodology, from the rea