In the title compound, C 43 H 36 Cl 2 N 4 O 3 Á0.5C 6 H 6 , there exists a trispiro ring system, which consists of a planar 2-oxindole ring, an envelope pyrrolidine ring, an envelope isoxazoline ring and a boat-shaped piperidone ring. The crystal structure is stabilized by NÐHÁ Á ÁN intermolecular i
Ring-Opening Reactions of 2-Phenyl-1’H,5H-spiro[oxazole-4,2’-quinoxalin]-3’(4’H)-ones
✍ Scribed by Verček, Bojan; Mušič, Irena
- Book ID
- 118255610
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 676 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0385-5414
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## Abstract Substituted 2‐(benzylamino)‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones are unstable under alkaline and acidic conditions, undergoing opening of the benzoxazinone ring. 2‐Bromo‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones show similar degradation under alkaline conditions, while replacement of Br at C
In the title compound, C 29 H 26 N 2 O 3 , the pyrrolidine ring adopts an envelope conformation and the cyclohexane ring adopts a chair conformation. The structure is stabilized by intramolecular CÐHÁ Á ÁO and %±% interactions.
2,3-Diphenyl-2,3-dihydrospiro[1,3-oxazole-5(4H),1 0 0 0 (3 0 0 0 H)-2-benzofuran]-3 0 0 0 -one