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Ring-opening polymerization of decamethylcyclopentasiloxane initiated by a superbase: Kinetics and rheology

โœ Scribed by Guillaume Pibre; Philippe Chaumont; Etienne Fleury; Philippe Cassagnau


Book ID
108249710
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
256 KB
Volume
49
Category
Article
ISSN
0032-3861

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Polymerization of 1-caprolactone had been investigated with cyclopentadienyl sodium as an initiator. The effects of reaction time, temperature, and concentration of the initiator on the yield and molecular weight of the polymer were discussed. It was shown that the high molecular weight of poly(1-ca