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Ring-opening polymerization of a five-membered lactone trans-fused to a cyclohexane ring

✍ Scribed by Haba, Osamu; Itabashi, Hiroki


Book ID
120979514
Publisher
Nature Publishing Group
Year
2013
Tongue
English
Weight
481 KB
Volume
46
Category
Article
ISSN
0032-3896

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The synthesis of a bis-cyclohexyl-fused penlaazamacrocycle via head-to-tail pseudopeptide cyclization chemistry is described. The bis-cyclohexyl-fused cyclic pseudopeptide 11 displays intramolecular hydrogen bonding which has been characterized by variable temperature NMR spectroscopy and X-Ray Crys