𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Ring opening of cyclohexene epoxide with trimethylsilyl cyanide

✍ Scribed by Gary O. Spessard; Allen R. Ritter; Dawn M. Johnson; Anne M. Montgomery


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
110 KB
Volume
24
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Efficient ring opening of epoxides with
✍ Antonio Procopio; Paola Costanzo; Renato Dalpozzo; Loredana Maiuolo; Monica Nard πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 607 KB

Epoxides can be opened under neutral conditions with TMSN 3 and TMSCN in the presence of catalytic amounts of Lewis acid, affording the corresponding ring-opened compounds in high yields.

Mechanistic insights into the opening of
✍ Paul G Gassman; Kentaro Okuma; Aline Lindbeck; Richard Allen πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 254 KB

endo-2,3-Epoxy-1,7,7-trimethylbicyclo[2.2.1]heptane reacted with trimethylsilyl cyanide in the pre=e of zinc iodide to produce a complex mixture of products. The major product, anti-7-trimethylsiloxy-endo-2,3,3-trimethyl-exo-2-isocyanobicyclo[2.2.l]heptane was obtained in f2%yield. -In addition, ei