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Efficient ring opening of epoxides with trimethylsilyl azide and cyanide catalyzed by erbium(III) triflate

✍ Scribed by Antonio Procopio; Paola Costanzo; Renato Dalpozzo; Loredana Maiuolo; Monica Nardi; Manuela Oliverio

Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
607 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis

Epoxides can be opened under neutral conditions with TMSN 3 and TMSCN in the presence of catalytic amounts of Lewis acid, affording the corresponding ring-opened compounds in high yields.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Erbium(III) Triflat
ChemInform Abstract: Erbium(III) Triflate Is a Highly Efficient Catalyst for the Synthesis of Ξ²-Alkoxy Alcohols, 1,2-Diols and Ξ²-Hydroxy Sulfides by Ring Opening of Epoxides.
✍ Renato Dalpozzo; Monica Nardi; Manuela Oliverio; Rosina Paonessa; Antonio Procop πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 59 KB πŸ‘ 2 views

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