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Ring opening of 1,3,2-oxazaphospholidine-2-thiones with alkyl lithiums; synthesis of chiral phosphinothioic acids

✍ Scribed by C.Richard Hall; Thomas D. Inch; Ian W. Lawston

Publisher: Elsevier Science
Year: 1979
Tongue: French
Weight: 214 KB
Volume: 20
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86400-5

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✦ Synopsis

Chn-al phosphmothlolc acids are prepared by a novel synthesis mvolvlng an unexpected P -0 bond cleavage with retention of conflguratlon at phosphorus.

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