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Ring-opening isomerization of methylenecyclopropanes catalyzed by hydridorhodium(I) complexes

โœ Scribed by Masumi Itazaki; Yasushi Nishihara; Hisami Takimoto; Chikako Yoda; Kohtaro Osakada


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
317 KB
Volume
241
Category
Article
ISSN
1381-1169

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Methylenecyclopropanes (MCPs) can react with aromatic amines to give the corresponding homoallylic amines in good to high yields in the presence of Lewis acids. The substituents on the benzene ring of the MCPs or the aromatic amines can affect significantly the reaction rate.

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