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A novel ring-opening reaction of methylenecyclopropanes with aromatic amines catalyzed by Lewis acids

✍ Scribed by Min Shi; Yu Chen; Bo Xu; Jie Tang

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
231 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Methylenecyclopropanes (MCPs) can react with aromatic amines to give the corresponding homoallylic amines in good to high yields in the presence of Lewis acids. The substituents on the benzene ring of the MCPs or the aromatic amines can affect significantly the reaction rate.

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