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Ring-opening desulfurization of 1,2,3-thiadiazolium salts with N-nucleophiles

✍ Scribed by L'abb�, Gerrit; Vossen, Peggy; Dehaen, Wim; Toppet, Suzanne

Book ID
120064515
Publisher
Royal Society of Chemistry
Year
1995
Weight
305 KB
Volume
17
Category
Article
ISSN
1472-7781

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~~~ ~ ~ ~ 4-Aryl-substituted 3,5-bis(methylthio)-1,2-dithiolium salts 9a, 10a were isolated. 4-Alkyl-substituted 1,3-bis(methylsuch as l a react with metal cyclopentadienides 4 (M+ = TI, thio)-1,2-dithiolium salts such as l c react with thallium cyclo-Li) mainly by cleavage of the S-S bond. A subseq