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Ring-Opening Copolymerization of Cyclotetrasilanes and Silicon-Bridged [1]Ferrocenophanes: Synthesis and Properties of Polysilane−Poly(ferrocenylsilane) Random Copolymers

✍ Scribed by Rulkens, Ron; Resendes, Rui; Verma, Atul; Manners, Ian; Murti, Krish; Fossum, Eric; Miller, Peter; Matyjaszewski, Krzysztof

Book ID
127014648
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
168 KB
Volume
30
Category
Article
ISSN
0024-9297

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📜 SIMILAR VOLUMES

Transition metal-catalyzed ring-opening
Transition metal-catalyzed ring-opening copolymerization of silicon-bridged [1]ferrocenophanes and sila- or disilacyclobutanes: Synthesis of poly(ferrocenylsilane)-poly(carbosilane) random copolymers
✍ John B. Sheridan; Paloma Gómez Elipe; Ian Manners 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 293 KB

## Abstract The first examples of poly(ferrocenylsilane)‐poly(carbosilane) random copolymers have been prepared via the transition metal‐catalyzed ring‐opening copolymerization of silicon‐bridged [1]ferrocenophanes and disila‐ or benzosilacyclobutane.

Transition Metal-Catalyzed Ring-Opening
Transition Metal-Catalyzed Ring-Opening Polymerization of Silicon-Bridged [1]Ferrocenophanes in the Presence of Functional Silanes: Molecular Weight Control and Synthesis of Telechelic Poly(ferrocenylsilanes)
✍ Alexandra Bartole-Scott; Rui Resendes; Ian Manners 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The transition metal‐catalyzed ring‐opening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fc = Fe(__η__‐C~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^