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Ring expansion of silacyclopentadienylcarbene to silabenzene

โœ Scribed by Wataru Ando; Hirohide Tanikawa; Akira Sekiguchi

Book ID
104221633
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
213 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Silacyclopentadienylmethylene generated from thermolysis and photolysis of l-methyl-2,3,4,5-tetraphenylsilacyclopentadienyldiazomethane and -diazirine rearranges to silabenzene by ring expansion and to 5-silafulvene by 1,2-migration of a methyl group.

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