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Ring expansion of .alpha.-hydroxyoxetanes to dihydrofurans

โœ Scribed by Farid, S.; Scholz, K. H.


Book ID
127294036
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
818 KB
Volume
37
Category
Article
ISSN
0022-3263

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Ring expansion of silacyclopentadienylca
โœ Wataru Ando; Hirohide Tanikawa; Akira Sekiguchi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 213 KB

Silacyclopentadienylmethylene generated from thermolysis and photolysis of l-methyl-2,3,4,5-tetraphenylsilacyclopentadienyldiazomethane and -diazirine rearranges to silabenzene by ring expansion and to 5-silafulvene by 1,2-migration of a methyl group.