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Ring expansion of 1-azirines to azepines via cycloaddition

✍ Scribed by Nair, V.


Book ID
126177296
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
366 KB
Volume
37
Category
Article
ISSN
0022-3263

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Synthesis of Substituted Dibenzo[a,d]aze
✍ Groth, U. ;Richter, L. ;SchΓΆllkopf, U. πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 413 KB

## Abstract Substituted dibenzoazepines 5 and 10 were synthesized in three steps by starting from acridine (6). The key step of the synthesis is a base‐mediated ring expansion reaction of the mesylates 1.