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Cycloadditions. XVIII. Reactions of 3H-azepines derived from cyclopentadienones and 1-azirines

✍ Scribed by Hassner, Alfred; Anderson, David J.; Tang, David


Book ID
127308635
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
601 KB
Volume
39
Category
Article
ISSN
0022-3263

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Photo-oxygenations of 1H-azepine derivat
✍ Tsutomu Kumagai; Akihiko Tokida; Kazuo Kidoura; Osamu Seshimoto; Toshio Mukai πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 235 KB

The reactions of lH-azepine derivatives (la\_b and 2) with singlet oxygen gave the [6+2] cycloadducts (2a\_b) and the [4+2] cycloadducts (3a\_b and 5). The thermal and base-catalyzed rearrangements of the oxygen-adducts were investigated. The manifold aspects related to the photo-oxygenation of carb