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Ring-cleavage rearrangement of the Grignard reagent from 2-methylcyclobutylmethyl chloride. Observations on possible radical mechanisms of Grignard rearrangement

โœ Scribed by Hill, E. Alexander; Chen, Augustin T.; Doughty, Alan


Book ID
127390713
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
492 KB
Volume
98
Category
Article
ISSN
0002-7863

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Substitution and rearrangement reactions
โœ Joseph D. Park; Raymond Sullivan; Randolph J. McMurtry ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 155 KB

Although the reaction of substituted fluoroolefins with nucleophiles, such as ethoxide, has received considerable attention in recent years (l), little is known concerning the subsequent attack by excess Grignard reagent on the initially formed substitution product in these systems.