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Rigidity factors in unimolecular reactions

✍ Scribed by Jürgen Troe

Book ID
112008621
Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
590 KB
Volume
101
Category
Article
ISSN
0372-8323

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It is assumed that A, in the limiting high-pressure unimolecular rate constant expression k , = A, exp(-E,,/kT) is given by A, = A,eRkT. The test case is the decomposition butane -2 ethyl, where a negative R reproduces the temperature dependence of A, about as well as the previously considered power