It is assumed that A, in the limiting high-pressure unimolecular rate constant expression k , = A, exp(-E,,/kT) is given by A, = A,eRkT. The test case is the decomposition butane -2 ethyl, where a negative R reproduces the temperature dependence of A, about as well as the previously considered power
โฆ LIBER โฆ
Frequency Factors in a Series of Similar Unimolecular Reactions
โ Scribed by SZWARC, M.; LEIGH, C. H.
- Book ID
- 109566678
- Publisher
- Nature Publishing Group
- Year
- 1951
- Tongue
- English
- Weight
- 219 KB
- Volume
- 167
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/167486a0
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