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Ribosomal Synthesis of Dehydroalanine-Containing Peptides

✍ Scribed by Seebeck, Florian P.; Szostak, Jack W.

Book ID
121320087
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
78 KB
Volume
128
Category
Article
ISSN
0002-7863

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Three model dipeptides containing a dehydroalanine residue ( AAla) at the C-terminal, Boc-X-AAla-NHCH3 [ X = Ala, Val, and Phe,] have been synthesized and their solution conformations investigated by 'H-NMR, IR, and CD spectroscopy. NMR studies on these peptides in CDCl, clearly indicate that the NH