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Rhodium(III)-Catalyzed Direct Regioselective Synthesis of 7-Substituted Indoles

✍ Scribed by Song, Zengqiang; Samanta, Rajarshi; Antonchick, Andrey P.


Book ID
121692754
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
501 KB
Volume
15
Category
Article
ISSN
1523-7060

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Ruthenium-catalyzed regioselective synth
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Anilines react with epoxides in dioxane at 180Β°C in the presence of a catalytic amount of a ruthenium catalyst along with tin(II) chloride to afford 2-substituted indoles in moderate to good yields.