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Ruthenium-catalyzed regioselective synthesis of 2-substituted indoles via ring-opening of epoxides by anilines

✍ Scribed by Chan Sik Cho; Jun Ho Kim; Heung-Jin Choi; Tae-Jeong Kim; Sang Chul Shim

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 87 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00396-4

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✦ Synopsis

Anilines react with epoxides in dioxane at 180°C in the presence of a catalytic amount of a ruthenium catalyst along with tin(II) chloride to afford 2-substituted indoles in moderate to good yields.

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