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Rhodium(II)-Catalyzed Addition of 2-Diazo(fluoroalkyl)acetoacetates to Sulfides: A Simple Synthesis of Stable Sulfonium Ylides.

โœ Scribed by Shizheng Zhu; Shifa Zhu; Yuanxi Liao


Book ID
101968703
Publisher
John Wiley and Sons
Year
2004
Weight
21 KB
Volume
35
Category
Article
ISSN
0931-7597

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Rhodium(II) acetate-catalyzed reaction o
โœ Edward C. Taylor; Huw M.L. Davies ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

Rhodium(I1) acetate-catalyzed decomposition of ethyl 2-diazo-3oxopent-4-enoates results in the formation of either 4-aryl-2-hydroxynaphthoates or 6,y-unsaturated esters. In the latter transformation, the dianion of 4-(diethylphosphono)acetoacetate functions as a propionate homoenolate equivalent.