✦ LIBER ✦

Rhodium(II)-Catalyzed Decomposition of 1-Diazo-4-(1- or 2-naphthyl)-2-butanones as a New Route to Rearranged Pimarane and Abietane Skeleta. Synthesis of Umbrosone

✍ Scribed by Manitto, Paolo; Monti, Diego; Speranza, Giovanna

Book ID: 118742247
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 400 KB
Volume: 62
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo970631k

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Rhodium(II)-Catalyz

ChemInform Abstract: Rhodium(II)-Catalyzed Decomposition of 1-Diazo-4-(1- or 2-naphthyl)-2-butanones as a New Route to Rearranged Pimarane and Abietane Skeleta. Synthesis of Umbrosone.

✍ P. MANITTO; D. MONTI; S. ZANZOLA; G. SPERANZA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB

Rhodium(II) acetate-catalyzed reaction o

Rhodium(II) acetate-catalyzed reaction of ethyl 2-diazo-3-oxopent-4-enoates: Simple routes to 4-aryl-2-hydroxy-1-naphthoates and β,β-unsaturated esters. The dianion of ethyl 4-(diethylphosphono)acetoacetate as a propionate homoenolate equivalent

✍ Edward C. Taylor; Huw M.L. Davies 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 170 KB

Rhodium(I1) acetate-catalyzed decomposition of ethyl 2-diazo-3oxopent-4-enoates results in the formation of either 4-aryl-2-hydroxynaphthoates or 6,y-unsaturated esters. In the latter transformation, the dianion of 4-(diethylphosphono)acetoacetate functions as a propionate homoenolate equivalent.