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Rhodium(II) acetate catalyzed hydrocarbon oxidations by molecular oxygen

✍ Scribed by Michael P. Doyle; Jan W. Terpstra; Charles H. Winter; John H. Griffin

Book ID
103692023
Publisher
Elsevier Science
Year
1984
Weight
559 KB
Volume
26
Category
Article
ISSN
0304-5102

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Rhodium-Catalyzed C,C-Double Bond Cleava
Rhodium-Catalyzed C,C-Double Bond Cleavage by Molecular Oxygen
✍ Helmut BΓΆnnemann; Washington Nunez; Dieter M. M. Rohe πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 328 KB

Acetylacetonatorhodiumolefin systems, allylrhodium complexes, or (Ph~3~P)~3~RhCl catalyzed the conversion of alkenes and molecular oxygen to carbonyl compounds __via__ Cο£ΎC‐bond cleavage. For example, 2,3‐dimethyl‐2‐butene was transformed into acetone. Butadiene and isoprene also undergo oxidative Cο£Ύ