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Rhodium(I)-Catalyzed Intramolecular Ene Reaction of Vinylidenecyclopropanes and Alkenes for the Formation of Bicyclo[5.1.0]octylenes

✍ Scribed by Li, Wei; Yuan, Wei; Shi, Min; Hernandez, Erik; Li, Guigen

Book ID: 126908792
Publisher: American Chemical Society
Year: 2010
Tongue: English
Weight: 311 KB
Volume: 12
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol902505p

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## Abstract **No templates needed**: The title reaction makes it easy to construct the bicyclo[6.3.0]undecadienone framework in high yields (see scheme). A template effect is not required to achieve this ring‐closing reaction efficiently. The present method can be applied to the construction of bic