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Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes

✍ Scribed by Fuyuhiko Inagaki; Katsuya Sugikubo; Yusuke Miyashita; Chisato Mukai

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 338 KB
Volume: 49
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200906994

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## Abstract **No templates needed**: The title reaction makes it easy to construct the bicyclo[6.3.0]undecadienone framework in high yields (see scheme). A template effect is not required to achieve this ring‐closing reaction efficiently. The present method can be applied to the construction of bic

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