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Rh(I)-Catalyzed Ring-Closing Reaction of Allenynes: Selective Construction of Cycloheptene, Bicyclo[5.3.0]decadienone, and Bicyclo[5.2.0]nonene Frameworks.

✍ Scribed by Chisato Mukai; Fuyuhiko Inagaki; Tatsunori Yoshida; Shinji Kitagaki

Publisher: John Wiley and Sons
Year: 2004
Weight: 176 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200435064

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## Abstract **No templates needed**: The title reaction makes it easy to construct the bicyclo[6.3.0]undecadienone framework in high yields (see scheme). A template effect is not required to achieve this ring‐closing reaction efficiently. The present method can be applied to the construction of bic