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Rhodium(I) bis(aminophosphane) complexes as catalysts for asymmetric hydrogenation of activated ketones

✍ Scribed by Alain Roucoux; Isabelle Suisse; Marc Devocelle; Jean-François Carpentier; Francine Agbossou; André Mortreux


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
238 KB
Volume
7
Category
Article
ISSN
0957-4166

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Cyclometalated Complexes of Ruthenium, R
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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the