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Chiral iridium(I) bis(NHC) complexes as catalysts for asymmetric transfer hydrogenation

✍ Scribed by Claus Diez; Ulrich Nagel


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
244 KB
Volume
24
Category
Article
ISSN
0268-2605

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Cyclometalated Complexes of Ruthenium, R
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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the