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Rhodium-Catalyzed Synthesis of Cyclohexenones via a Novel [4 + 2] Annulation

✍ Scribed by Tanaka, Ken; Fu, Gregory C.


Book ID
126161869
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
44 KB
Volume
4
Category
Article
ISSN
1523-7060

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## Abstract The reaction mechanism of the Rh‐catalyzed [4 + 2] annulation of 4‐alkynals with isocyanates is unraveled using density functional calculations. The reaction mechanisms of the model system and the real substituted system have been investigated and the results are compared. From our theo