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Rhodium Catalyzed ortho -Cyanation of Arylphosphates with N -cyano- N -phenyl- p -toluenesulfonamide

โœ Scribed by Gu, Li-Jun; Jin, Cheng; Wang, Rui; Ding, Hong-Yan


Book ID
127046554
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
265 KB
Category
Article
ISSN
1867-3880

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Palladium-catalyzed cascade reactions of
โœ Yi-min Hu; Jie Zhou; Xiang-tian Long; Jian-lin Han; Chen-jian Zhu; Yi Pan ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 79 KB

Reaction of benzyl halides with N-allyl-N-(2-butenyl)-p-toluenesulfonamide 1 in the presence of a palladium catalyst afforded dihydropyrroles 3 in moderate to excellent yields. It is proposed that the cyclic products were formed via a palladium-catalyzed cascade cyclization-coupling process.