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Palladium-catalyzed cascade reactions of benzyl halides with N-allyl-N-(2-butenyl)-p-toluenesulfonamide

✍ Scribed by Yi-min Hu; Jie Zhou; Xiang-tian Long; Jian-lin Han; Chen-jian Zhu; Yi Pan

Book ID: 104253851
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 79 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01177-8

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✦ Synopsis

Reaction of benzyl halides with N-allyl-N-(2-butenyl)-p-toluenesulfonamide 1 in the presence of a palladium catalyst afforded dihydropyrroles 3 in moderate to excellent yields. It is proposed that the cyclic products were formed via a palladium-catalyzed cascade cyclization-coupling process.

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