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Rhodium-Catalyzed Intramolecular Alkyne-carbodiimide Pauson—Khand-Type Reaction.

✍ Scribed by Takao Saito; Katsuya Sugizaki; Takashi Otani; Toshiyuki Suyama


Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Asymmetric Aqueous Pau
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## Abstract An interesting rhodium‐catalyzed asymmetric aqueous Pauson–Khand‐type reaction was developed. A chiral atropisomeric dipyridyldiphosphane ligand was found to be highly effective in this system. This operationally simple protocol allows both catalyst and reactants to be handled under air

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