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Rhodium-Catalyzed Intermolecular [2+2+2] Cross-Trimerization of Aryl Ethynyl Ethers and Carbonyl Compounds To Produce Dienyl Esters

✍ Scribed by Yuta Miyauchi; Masayuki Kobayashi; Prof. Dr. Ken Tanaka

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 383 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201105519

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## Abstract A cationic Rh(I)‐H~8~‐BINAP complex efficiently catalyzes the cross [2 + 2 + 2] cycloaddition of aryl ethynyl ethers (I) with internal alkynes (II) and homo [2 + 2 + 2] cycloaddition of (I).