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ChemInform Abstract: Synthesis of Tri- and Diaryloxybenzenes by Rhodium-Catalyzed Complete Intermolecular [2 + 2 + 2] Cycloaddition of Aryl Ethynyl Ethers.

✍ Scribed by Yoshiyuki Komine; Yuta Miyauchi; Masayuki Kobayashi; Ken Tanaka

Publisher: John Wiley and Sons
Year: 2011
Weight: 35 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201116066

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✦ Synopsis

Abstract

A cationic Rh(I)‐H~8~‐BINAP complex efficiently catalyzes the cross [2 + 2 + 2] cycloaddition of aryl ethynyl ethers (I) with internal alkynes (II) and homo [2 + 2 + 2] cycloaddition of (I).

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ChemInform Abstract: Rhodium-Catalyzed Complete Regioselective Intermolecular Cross-Cyclotrimerization of Aryl Ethynyl Ethers and Nitriles or Isocyanates at Room Temperature.

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