water is usually recognized as a strong inhibitor of transition-metal polymerization. By analyzing the addition order effect of the ingredients, we show that the reduction of cobalt in the presence of butadiene is necessary for the polymerization. Radical-polymerization inhibitors such as phenols di
Rhodium-catalyzed emulsion polymerization of butadiene
β Scribed by Morton, Maurice ;Das, B.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 248 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0449-2994
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The kinetics of the ferric ethylenediaminetetraacetate (EDTA)βdiisopropylbenzene hydroperoxide (DIBHP)βsodium formaldehyde sulfoxylate (SFS) redox system were determined. The rate constant is a function of the ionic strength ΞΌ. A plot of log~10~ (rate constant), for the rateβlimiting se
ln order to adapt the reduction-activation reaction of hydrogen peroxide to the polymerization of 2-phenyl-l,3-butadiene, emulsion polymerization was carried out with H202/Fe 2+ as catalyst in the presence of sodium pyrophosphate. The influences of emulsifier, iron ligand, electrolyte salt and polym