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Rhodium-Catalyzed Asymmetric Addition of Organo-Boron and -Titanium Reagents to Electron-Deficient Olefins

✍ Scribed by Tamio Hayashi

Publisher
John Wiley and Sons
Year
2004
Weight
68 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9