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Rhodium catalyzed asymmetric 1,4-addition of arylboronic acids to β,γ-unsaturated α-keto ester using chiral tert-butanesulfinylphosphines ligands

✍ Scribed by Wang, Juanjuan; Wang, Bing; Cao, Peng; Liao, Jian


Book ID
122106322
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
482 KB
Volume
55
Category
Article
ISSN
0040-4039

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9