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Rh(iii)-catalyzed ortho-oxidative alkylation of unactivated arenes with allylic alcohols

✍ Scribed by Huang, Liangbin; Wang, Qian; Qi, Ji; Wu, Xia; Huang, Kefan; Jiang, Huanfeng

Book ID: 120333056
Publisher: The Royal Society of Chemistry
Year: 2013
Tongue: English
Weight: 306 KB
Volume: 4
Category: Article
ISSN: 2041-6520
DOI: 10.1039/C3SC50630D

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## Abstract “__Deficient” but “efficient__”, the first example of a catalytic Friedel–Crafts alkylation of arenes, carrying electron‐withdrawing groups, with alcohols is reported. The optimized iron(III) chloride (97%) catalyzed allylation, benzylation and propargylation procedures open an access t