Ligand-Free Silver(I)-Catalyzed Intramolecular Friedel–Crafts Alkylation of Arenes with Allylic Alcohols

Iron(III)-Catalyzed Intramolecular Fried

Iron(III)-Catalyzed Intramolecular Friedel–Crafts Alkylation of Electron-Deficient Arenes with π-Activated Alcohols

✍ Marco Bandini; Michele Tragni; Achille Umani-Ronchi 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB 👁 2 views

## Abstract “__Deficient” but “efficient__”, the first example of a catalytic Friedel–Crafts alkylation of arenes, carrying electron‐withdrawing groups, with alcohols is reported. The optimized iron(III) chloride (97%) catalyzed allylation, benzylation and propargylation procedures open an access t