Rheokinetics of free-radical polymerization
β Scribed by A.Ya Malkin; S.G. Kulichikhin; D.N. Emel'yanov; I.E. Smetanina; N.V. Ryabokon'
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 617 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0032-3861
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A kinetic model has been developed for stable free-radical polymerization (SFRP) processes by using the method of moments. This model predicts monomer conversion, number-average molecular weight, and polydispersity of molecular weight distribution. The effects of the concentrations of initiator, sta
&&Living'' free-radical polymerization (LFRP) of styrene is usually performed following two di!erent reaction procedures: by TEMPO-mediated LFRP or by atom transfer radical polymerization. The main di!erence between the previous two processes is related to how the exchange between the active and the