Rhenium(V) Oxo Complexes with Acetylacetone Derived Schiff Bases: Structure and Catalytic Epoxidation
✍ Scribed by Wielandt, J. Wolfram; Most, Kerstin; Magull, Jörg; Dall'Antonia, Fabio; Pal, Aritra; Herbst-Irmer, Regine; Sachse, Anna; Mösch-Zanetti, Nadia C.; Lyashenko, Ganna
- Book ID
- 115539237
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 170 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0020-1669
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A series of monooxo-rhenium(V) mixed-ligand complexes containing bidentate functionalized phosphines and tridentate Schiff base (SB) ligands have been synthesized via ligand-exchange reactions starting from labile Re(V) precursors. A convenient route of synthesis is provided by the isolation of inte
## Abstract Several Schiff‐base ligands readily form complexes with methyltrioxorhenium(VII) (MTO) by undergoing a hydrogen transfer from a ligand‐bound OH group to a ligand N atom. The resulting complexes are stable at room temperature and can be handled and stored in air without problems. Due to