Rhenium(Ill) and (V) complexes with schiff bases
โ Scribed by A. Marchi; A. Duatti; R. Rossi; L. Magon; E. Roncari; U. Mazzi
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 196 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1693
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A series of monooxo-rhenium(V) mixed-ligand complexes containing bidentate functionalized phosphines and tridentate Schiff base (SB) ligands have been synthesized via ligand-exchange reactions starting from labile Re(V) precursors. A convenient route of synthesis is provided by the isolation of inte
Reaction of trichloro-0x0-bis (triphenylphosphine) rhenium (V) and Schiff bases derived from some aliphatic diamines and 2-hydroxy-1-naphthaldehyde in the presence of triethylamine gives as anionic complex (ReOLC12)-, where L is a tetradentate Schiff base ligand. On the basis of various physical pro