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RhCl(PPh3)3/DPPF: A Useful and Efficient Catalyst for Cross-Coupling Reactions of Activated Alkenyl Tosylates with Arylboronic Acids

✍ Scribed by Jie Wu; Liang Zhang; Ke Gao

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 95 KB
Volume: 2006
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200600469

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can