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RhCl(PPh3)3/DPPF: A Useful and Efficient Catalyst for Cross-Coupling Reactions of Activated Alkenyl Tosylates with Arylboronic Acids.

✍ Scribed by Jie Wu; Liang Zhang; Ke Gao

Publisher: John Wiley and Sons
Year: 2007
Weight: 31 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200712141

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RhCl(PPh3)3/DPPF: A Useful and Efficient

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Pd/P(i-BuNCH2CH2)3N: an efficient cataly

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Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can