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Rh-Catalyzed asymmetric hydrogenation of (Z)-ethyl 3-acetamido-2-butenoate in supercritical carbon dioxide: the effect of cosolvents

✍ Scribed by S. E. Lyubimov; E. A. Rastorguev; P. V. Petrovskii; V. A. Davankov


Publisher
Springer
Year
2011
Tongue
English
Weight
164 KB
Volume
60
Category
Article
ISSN
1573-9171

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Application of a new amidophosphite liga
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## Abstract New chiral amidophosphite ligand was synthesized and tested in the Rh‐catalyzed asymmetric hydrogenation of (__Z__)‐β‐(acylamino)acrylates in protic solvents and supercritical carbon dioxide (scCO~2~) The catalytic performance is affected greatly by the acidity of the solvents. Better e