Revision of the absolute stereochemistry of ilimaquinone
β Scribed by Capon, Robert J.; MacLeod, John K.
- Book ID
- 127091826
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 278 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-3263
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## Abstract For Abstract see ChemInform Abstract in Full Text.
In the previous paper, we reported the stereochemistry of coronatine 1) , in which amino acid part, (+) -coronamic acid, was described as the enantiomer ofA on the basis of application of sector rule. 3) In this communication, we would like to describe further investigation on the stereochemistry of
The first stereoselective total synthesis of synargentolide A isolated from Syncolostemon argenteus has been achieved from commercially available (R)-benzyl glycidyl ether using Sharpless asymmetric epoxidation and cross-metathesis reactions as the key steps. Comparing the spectral data of the synth