Reversible β-hydrogen transfer between Fe(C2H5)+ and HFe(C2H4)+: case of two-state reactivity?
✍ Scribed by Andreas Fiedler; Detlef Schröder; Waltraud Zummack; Helmut Schwarz
- Book ID
- 108328524
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 865 KB
- Volume
- 259
- Category
- Article
- ISSN
- 0020-1693
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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit
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