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Reversible, Room-Temperature Ionic Liquids. Amidinium Carbamates Derived from Amidines and Aliphatic Primary Amines with Carbon Dioxide

โœ Scribed by Yamada, Taisuke; Lukac, Paul Joseph; George, Mathew; Weiss, Richard G.


Book ID
111924476
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
64 KB
Volume
19
Category
Article
ISSN
0897-4756

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The syntheses of carbamates from reactio
โœ Tianlong Sima; Shu Guo; Feng Shi; Youquan Deng ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 91 KB

At 170ยฐC and using ionic liquids as solvent and catalyst, primary and secondary aliphatic amines could react with dimethyl carbonate to give alkyl carbamates with good yield. Due to its insolubility, the desired carbamate solid could be recovered by simple filtration from the two-layer mixture of di