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Reversible carbon monoxide binding to iron(III) isobacteriochlorins

✍ Scribed by Sullivan, Eric P.; Strauss, Steven H.


Book ID
126848935
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
424 KB
Volume
28
Category
Article
ISSN
0020-1669

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Solutions of several iron(I1) thiolato complexes in methanol, dimethylformamide or 2-ethoxyethanol reversibly absorb and release carbon monoxide at atmospheric pressure and 20-50 "C. Solutions of Fe(SPh),(H,NCH,CH,NHJ (CO), and of an anionic complex tentatively formulated as [Fe2(SPh),(CO),]-in 2-et