Iron(II) thiolates as reversible carbon
β
AnikΓ³ SzakΓ‘cs-Schmidt; JΓ³zsef Kreisz; LΓ‘szlo MarkΓ³; Zsuzsa Nagy-Magos; JΓ‘nos Tak
π
Article
π
1992
π
Elsevier Science
π
English
β 556 KB
Solutions of several iron(I1) thiolato complexes in methanol, dimethylformamide or 2-ethoxyethanol reversibly absorb and release carbon monoxide at atmospheric pressure and 20-50 "C. Solutions of Fe(SPh),(H,NCH,CH,NHJ (CO), and of an anionic complex tentatively formulated as [Fe2(SPh),(CO),]-in 2-et